Extractive Metallurgy of Activated MineralsElsevier, 28 квіт. 2000 р. - 292 стор. Mechanical activation of solids is a part of mechanochemistry, the science with a sound theoretical foundation exhibiting a wide range of potential application. Mechanical activation itself is an innovative procedure where an improvement in technological processes can be attained via a combination of new surface area and defects formation in minerals. Mechanical activation is of exceptional importance in extractive metallurgy and mineral processing and this area forms the topic of this book and is the result of more than twenty years of research and graduate teaching in the field. In pyrometallurgy, the mechanical activation of minerals makes it possible to reduce their decomposition temperatures or causes such a degree of disordering that the thermal activation may be omitted entirely. The potential mitigation of environmental pollutants is becoming increasingly important in this context. The lowering of reaction temperatures, the increase of the rate and amount of solubility, preparation of water soluble compounds, the necessity for simpler and less expensive reactors and shorter reaction times are some of the advantages of mechanical activation in hydrometallurgy. The environmental aspects of these processes are particularly attractive. Several industrial processes are examined and their flowsheets are presented as succesful of activation. In these processes, the introduction of a mechanical activation step into the technological cycle significantly modifies the subsequent steps. The book is designed for researchers, teachers, operators and students in the areas of extractive metallurgy, mineral processing, mineralogy, solid state chemistry and materials science.It will encourage newcomers to the mechanochemistry to do useful research and discover novel applications in this field. |
Зміст
1 | |
15 | |
CHAPTER 3 PHYSICOCHEMICAL PROPERTIES OF MECHANICALLY ACTIVATED MINERALS | 35 |
CHAPTER 4 POLYMORPHOUS TRANSFORMATIONS INDUCED IN MINERALS BY MECHANICAL ACTIVATION | 81 |
CHAPTER 5 THERMAL DECOMPOSITION OF MECHANICALLY ACTIVATED MINERALS | 95 |
CHAPTER 6 CHEMICAL LEACHING OF MECHANICALLY ACTIVATED MINERALS | 143 |
CHAPTER 7 INFLUENCE OF MECHANICAL ACTIVATION ON BACTERIAL LEACHING OF MINERALS | 195 |
CHAPTER 8 MECHANICAL ACTIVATION IN TECHNOLOGY | 213 |
SUMMARY | 265 |
267 | |
274 | |
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Загальні терміни та фрази
acid activation energy adsorption agglomerates amorphization antimony arsenic arsenopyrite atoms attritor Avvakumov bacterial leaching Baláž ball mill chalcopyrite chalcopyrite concentrate changes chemical leaching copper CuFeS2 curves cyanide decrease diffraction line dry grinding electron equation exothermic Extractive Metallurgy FeAsS ferric sulfate FeS2 formation galena gold Hydrometallurgy increase influence of mechanical infrared infrared spectroscopy ions iron lattice leaching agent magnetic mechanical activation mechanically activated samples Mechanochemistry metals method Moscow Mössbauer Mössbauer effect Mössbauer spectroscopy Nauka non-activated sample Novosibirsk parameters particles peak pentlandite phase planetary mill present pretreatment Proc pyrite pyrrhotite rate constant ratio reaction reactivity recovery represented in Fig Russian sample activated sample mechanically activated Selective leaching silver solution specific adsorption surface specific surface area spectra spectroscopy sphalerite stibnite structural disorder Table temperature tetrahedrite tetrahedrite concentrate thermal decomposition Tkáčová transformation ultrafine grinding V.V. Boldyrev values vibration mill X-ray zinc