The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6), Томи 1 – 6

Передня обкладинка
L.R. Morss, Norman M. Edelstein, Jean Fuger
Springer Science & Business Media, 21 жовт. 2010 р. - 4503 стор.

The fourth edition of "The Chemistry of the Actinide and Transactinide Elements" comprises all chapters in volumes 1 through 5 of the third edition (published in 2006) plus a new volume 6. To remain consistent with the plan of the first edition, “ ... to provide a comprehensive and uniform treatment of the chemistry of the actinide [and transactinide] elements for both the nuclear technologist and the inorganic and physical chemist,” and to be consistent with the maturity of the field, the fourth edition is organized in three parts.

The first group of chapters follows the format of the first and second editions with chapters on individual elements or groups of elements that describe and interpret their chemical properties. A chapter on the chemical properties of the transactinide elements follows. The second group, chapters 15-26, summarizes and correlates physical and chemical properties that are in general unique to the actinide elements, because most of these elements contain partially-filled shells of 5f electrons whether present as isolated atoms or ions, as metals, as compounds, or as ions in solution. The third group, chapters 27-39, focuses on specialized topics that encompass contemporary fields related to actinides in the environment, in the human body, and in storage or wastes. Two appendices at the end of volume 5 tabulate important nuclear properties of all actinide and transactinide isotopes. Volume 6 (Chapters 32 through 39) consists of new chapters that focus on actinide species in the environment, actinide waste forms, nuclear fuels, analytical chemistry of plutonium, actinide chalcogenide and hydrothermal synthesis of actinide compounds. The subject and author indices and list of contributors encompass all six volumes.

 

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Зміст

INTRODUCTION
1
ACTINIUM
18
THORIUM
52
PROTACTINIUM
161
URANIUM
253
NEPTUNIUM
699
PLUTONIUM
813
AMERICIUM
1265
ACTINIDE STRUCTURAL CHEMISTRY
2380
ACTINIDES IN SOLUTION COMPLEXATION AND KINETICS
2524
ACTINIDE SEPARATION SCIENCE AND TECHNOLOGY
2622
ORGANOACTINIDE CHEMISTRY SYNTHESIS AND CHARACTERIZATION
2799
HOMOGENEOUS AND HETEROGENEOUS CATALYTIC PROCESSES PROMOTED BY ORGANOACTINIDES
2911
IDENTIFICATION AND SPECIATION OF ACTINIDES IN THE ENVIRONMENT
3013
XRAY ABSORPTION SPECTROSCOPY OF THE ACTINIDES
3086
HANDLING STORAGE AND DISPOSITION OF PLUTONIUM AND URANIUM
3199

CURIUM
1397
BERKELIUM
1444
CALIFORNIUM
1499
EINSTEINIUM
1577
FERMIUM MENDELEVIUM NOBELIUM AND LAWRENCIUM
1621
TRANSACTINIDE ELEMENTS AND FUTURE ELEMENTS
1652
SUMMARY AND COMPARISON OF PROPERTIES OF THE ACTINIDE AND TRANSACTINIDE ELEMENTS
1753
SPECTRA AND ELECTRONIC STRUCTURES OF FREE ACTINIDE ATOMS AND IONS
1836
THEORETICAL STUDIES OF THE ELECTRONIC STRUCTURE OF COMPOUNDS OF THE ACTINIDE ELEMENTS
1893
OPTICAL SPECTRA AND ELECTRONIC STRUCTURE
2013
THERMODYNAMIC PROPERTIES OF ACTINIDES AND ACTINIDE COMPOUNDS
2113
MAGNETIC PROPERTIES
2225
5fELECTRON PHENOMENAIN THE METALLIC STATE
2307
RACE ANALYSIS OF ACTINIDES IN GEOLOGICAL ENVIRONMENTAL AND BIOLOGICAL MATRICES
3273
ACTINIDES IN ANIMALS AND MAN
3339
ACTINIDES IN THE GEOSPHERE
3475
SUBSURFACE INTERACTIONS OF ACTINIDE SPECIES WITHMICROORGANISMS
3595
NUCLEAR FUELS
3665
ACTINIDE WASTE FORMS AND RADIATION EFFECTS
3813
ANALYTICAL CHEMISTRY OF PLUTONIUM
3889
ACTINIDE CHALCOGENIDE COMPOUNDS
4005
MOLECULAR SPECTROSCOPY AND REACTIONS OF ACTINIDES IN THE GAS PHASE AND CRYOGENIC MATRICES
4079
HYDROTHERMAL SYNTHESIS AND CRYSTAL STRUCTURES OF ACTINIDE COMPOUNDS
4157
SUBJECT INDEX
I-1
AUTHOR INDEX
I-159
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Про автора (2010)

  • Lester R. Morss is the Program Manager for Heavy Element Chemistry at the Office of Science , U.S. Department of Energy in Germantown, Maryland, USA. He was taught actinide chemistry fbyProfessor Burris B. Cunningham, his Ph.D. mentor at the University of California, Berkeley and from 1971 to 1980 he was a member of the chemistry faculty at Rutgers University, New Brunswick, New Jersey, USA. In 1980, Dr. Morss moved to the Argonne National Laboratory (Illinois, USA), where he remained as an actinide chemist until 2002 . At all of these institutions he carried out research in the inorganic chemistry of lanthanide and actinide elements, with a focus on transuranium elements. His publications were primarily in thermochemistry and structure-bonding relationships among metals, oxides, halides, and coordination complexes. Dr. Morss has had fellowships at the University of Liege, Belgium and at the University of Hannover, Germany (von Humboldt Senior Scientist) and he is also a fellow of the American Association for the Advancement of Science.

  • Norman Edelstein is an emeritus Senior Scientist at the Lawrence Berkeley National Laboratory (LBNL). He started his studies in actinide chemistry with Professor Burris B. Cunningham in 1964 at LBNL (then the University of California Radiation Laboratory), USA. Following Professor Cunningham’s untimely death in 1972 he became head of the actinide chemistry group and held that position until his assignment in 2000 and 2001 as temporary Program Manager for Heavy Element Chemistry at the Office of Science, U.S. Department of Energy, Germantown, Maryland, USA. His primary research interests are the optical properties, magnetic properties, and electronic structure of the actinides and lanthanides; the general, inorganic and solution chemistry of the actinides; and synchrotron radiation studies of actinides and other environmentally relevant materials. Dr. Edelstein has published over 200 papers on these and other topics and has edited three other volumes on actinide subjects.

  • Jean Fuger is Professor Emeritus at the University of Liège, Belgium, where he has taught courses in radiochemistry, analytical chemistry, and related subjects. In the early stages of his career, whilst associated with the Inter-University Institute for Nuclear Sciences (Brussels, Belgium), he made extensive stays at the University of California Radiation Laboratory, Berkeley, USA, with Professor Burris B. Cunningham, from whom he learned various microchemical techniques in actinide chemistry, with emphasis on preparative chemistry and microcalorimetry. From 1986 to 1997 he served as head of the chemistry division and later as deputy director of the European Institute for Transuranium Elements, Karlsruhe, Germany. His research interests are centered on the structural and thermodynamic properties of the lanthanides and actinides and their compounds, as well as the solution chemistry of these elements. He published about 125 papers, and 20 monographs and book chapters on these topics.

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