The Chemistry of ExplosivesRoyal Society of Chemistry, 2004 - Počet stran: 180 Revised and expanded to reflect new developments in the field, this book outlines the basic principles required to understand the chemical processes of explosives. The Chemistry of Explosives provides an overview of the history of explosives, taking the reader to future developments. The text on the classification of explosive materials contains much data on the physical parameters of primary and secondary explosives. The explosive processes of deflagration and detonation, including the theory of 'hotspots' for the detonation process, are introduced and many examples are provided in the detailed description on the thermochemistry of explosives. New material includes coverage of the latest explosive compositions, such as high temperature explosives, nitrocubanes, energetic polymers, plasticizers and insensitive munitions (IM). This concise, readable book is ideal for 'A' level students and new graduates with no previous knowledge of explosive materials. With detailed information on a vast range of explosives in tabular form and an extensive bibliography, this book will also be useful to anyone needing succinct information on the subject. |
Obsah
Chapter | 1 |
Chapter 2 | 21 |
V111 | 22 |
Other Compounds used in Explosive Compositions | 47 |
Classification of Explosives | 62 |
Initiation Techniques | 70 |
Decomposition Reactions | 77 |
Heat of Explosion | 83 |
Kinetics of Explosive Reactions | 111 |
Chapter 7 | 118 |
ONitration | 125 |
NNitration | 131 |
Commercial Explosive Compositions | 141 |
Chapter 8 | 149 |
Gasgenerating Propellants | 157 |
| 165 | |
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a-form aluminium ammonium nitrate atoms blackpowder blasting burning rate calculated carbon dioxide carbon monoxide CH₂ONO2 chemical explosion Colour Molecular weight combustion commercial explosives components compounds contain crystalline solid decomposition products deflagration density at 20 developed dm³ dynamite Enthalpy of formation/kJkg-1 explosive composition Explosive material explosive substances friction fuel gaseous products gases gun propellants H₂C CH2 heat of explosion hotspots hydrogen increase initiation Kistiakowsky-Wilson rules kJ mol-1 lead azide Lead styphnate liquid manufacturing Melting temperature/°C mercury fulminate mixed mixture molecules n₁ nitro nitrocellulose nitrogen nitroglycerine Nitroguanidine NO2 NO2 NO2 O2N O₂N O2N NO2 oxidation oxygen balance PBXs perchlorate PETN picric acid potassium prepared presented in Table pressure Primary explosives properties pyrotechnic compositions rocket propellants secondary explosives shockwave shown in Equation shown in Figure shown in Reaction TATB temperature of explosion Tetrazene Tetryl Thermal ignition temperature/°C tion TNAZ velocity of detonation ΔΗ ΔΗ₁
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